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《International Journal of Hydrogen Energy》2023,48(41):15447-15459
In this study, a new strategy has been produced to use a rotten apple juice as a source for the surface modification of Co3O4 nanostructures, giving rise to efficient electro-catalysts for driving oxygen evolution reaction (OER) at relatively low over potential. We have studied the morphology, chemical composition, and crystalline aspects of Co3O4 nanostructures using different analytical techniques. The Co3O4 nanostructures grown with rotten apple juice were observed with low impurity of Fe and P, surface modification, reduced particle size, high concentration of oxygen vacancies, defects and cubic phase of Co3O4. Furthermore, we have used the surface modified Co3O4 nanostructures for water electrolysis and noticed the significant performance towards OER in alkaline conditions. The electrochemical characterization revealed that the Co3O4 nanostructure prepared with 20 mL of rotten apple juice exhibits an overpotential value of 269 mV at 20 mA/cm2 current density. The charge transport resistance (Rct) at the interface was estimated around 118.9 Ω, confirming an excellent reaction kinetics on the Co3O4 nanostructures and highly supported efficient performance towards OER. The Co3O4 nanostructures prepared with 20 mL of rotten apple juice has shown an acceptable durability for 40 h, verifying the long-term use. The performance of Co3O4 nanostructures with apple juice could be attributed to high oxygen vacancies due to high density of Co2+ ions on the surface, impurities of Fe and P, reduced nanoparticle size, defects in the structures, and favorable chemical composition. At the end, surface modified Co3O4 nanostructures was observed as an outperformed electrocatalyst when prepared with rotten apple juice. Therefore, this can be used in diverse purposes including energy conversion and storage applications. 相似文献
74.
25%虫螨克乳油是一种广谱性杀虫杀螨剂,具有触杀和胃毒作用,且有一定的杀卵活性。经1993 ̄1994年试验证明,虫螨克对梨木虱防效显著,能有效地控制苹果黄蚜和山楂叶螨等虫螨的为害。 相似文献
75.
In this paper, three different processes for puree extraction from Golden Delicious apples and enzyme inactivation are analyzed and compared: (i) hot extraction technique, (ii) cold extraction technique and (iii) a newly developed vacuum puree extraction technology (Zenith Chrono®). The analysis was carried out by means of manual laboratory operations reproducing the three processes. The primary objective of this study was the evaluation of the minimum amount of ascorbic acid that must be added to the three fruit purees in order to contain oxidization and color change in the products. Afterwards, the residual enzymatic activity was checked and characteristics of the products were compared (i.e. fraction of dried solids and consistency of the puree). All of the processes achieved complete enzyme deactivation and an imperceptible color change, and the results of this paper support interest in vacuum puree extraction technology. 相似文献
76.
P.L. Gómez A. García-Loredo D.M. Salvatori S. Guerrero S.M. Alzamora 《Journal of food engineering》2011,107(2):214-225
The aim of this work was to analyze the effect of UV-C radiation (fluence: 11.2 kJ/m2), with or without an anti-browning pretreatment containing 1% (w/v) ascorbic acid plus 0.1% (w/v) calcium chloride, on the linear viscoelastic properties (oscillatory shear and creep/recovery), instrumental texture (TPA), sensory texture and ultrastructure (ESEM, TEM) of cut apple. Changes in structural features and viscoelastic parameters were mainly evidenced after refrigerated storage. All samples showed a viscoelastic solid behavior with the storage modulus (G′) dominating the viscoelastic response. Overall, both dynamic moduli decreased, and instantaneous compliance (J0), decay compliances (J1 and J2) and fluidity significantly increased after treatments and storage at 5 °C, while retardation times were in general constant. Fracture properties proved to be the most highly correlated with sensory texture. The test panel only significantly differentiated stored untreated apple from the other samples regarding fracturability and juiciness. Mechanical spectra and creep parameters showed ability to evidence ultrastructural differences (rupture of membranes, swelling of cells, alteration of cell walls) in the surface of cut apples subjected to the different treatments. 相似文献
77.
Manal M. Housseiny Heba I. Abo‐Elmagd Gamil E. Ibrahim 《International Journal of Food Science & Technology》2013,48(11):2292-2299
This research deals with the production of water‐soluble polysaccharides from six polysaccharide‐producing Penicillium species. Eup. pinetorum ATCC 14770 was promising for exo‐ and endopolysaccharides production under various cultural conditions. pH 5.0, 7 days, and pH 8.0, 10 days, were the optimum for the production of exo‐ and endopolysaccharides, respectively, at 30 °C in medium containing glucose and peptone. HPLC results revealed that both polysaccharides were composed of pectin, cellulose and hemicellulose. Exopolysaccharides produced by Eup. pinetorum was subjected to evaluation as a natural flavour stabiliser in cloudy apple juice (CAJ). Twenty‐one volatile compounds classified into esters, aldehydes, alcohols and ketone were detected, only eighteen compounds of which were characterised by their odours threshold. The esters and alcohols are accounting for 87.64% and 5.44% of total volatiles, respectively. This study indicates that the use of exopolysaccharides as an alternative flavour stabiliser in CAJ is very promising. 相似文献
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79.
M. Duenas A. Irastorza C. Fernandez A. Bilbao G. Del Campo A. Munduate 《Journal of the Institute of Brewing》1997,103(4):251-255
This study was conducted to examine the influence of the following apple juice treatments on different parameters of cidermaking process: sulphiting (50 mg/L of total S02), clarification with pectolytic enzymes (Ultrazym 100 G, 3g/hL), and bentonite fining (lOOg/hL). The different treatments slowed down alcoholic fermentation, the greatest effect being found for the combination of the three treatments. With respect to malolactic fermentation, must sulphiting, with or without the other two treatments, delayed this process, which took place after alcoholic fermentation. The low levels of lactic acid bacteria during this period can explain this delay. The only treatment that had any significant influence on volatile acidity was sulphiting, either on its own or in combination with the other treatments. Thus lower acetic acid levels were detected in ciders treated with SO2 . 相似文献
80.
ABSTRACT: Vacuum hydrodistillation, which is a very gentle work-up procedure, has never been used for the extraction of apple aroma. During the concentration of aroma that follows vacuum hydrodistillation, some very volatile components can be lost. The aim of this study was to compare 2 different concentration techniques, liquid-liquid extraction and solid phase extraction, to obtain an apple aroma extract as close as possible to fresh apple. After the elimination of solvent from the extract by gas chromatography, the study of the odor characteristics of solvent-free extracts was made possible. Vacuum hydrodistillation was convenient for fresh apples. 相似文献